The iron-catalyzed hydrosilylation of alkynes undergoes two potential energy surfaces, the triplet (red) and quintet (blue) states, where the spin crossover effectively lowers the reaction energy ...
Liang Deng's group at the Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, recently discovered that a dinuclear cobalt carbonyl complex [(Xantphos)Co2(CO)6] coordinated by the ...
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